4)金属富勒烯的光磁性质研究。金属富勒烯单分子磁体具有独特的结构和性质,富勒烯笼将磁性金属离子保护并与其他磁性离子隔离开来,在量子比特方面具有重要的研究价值。为了便于信息的写入与读取,将光学特性集成到富勒烯笼内并实现金属富勒烯单分子磁体的光磁相互作用具有重要意义。我们将金属Er和Dy同时嵌入到富勒烯笼内,将Dy离子的单分子磁体功能和Er离子的近红外荧光特性结合起来,设计、合成、表征了一系列发光的单分子磁体,探究了结构、温度等条件对发光单分子磁体的影响,推动单分子磁体的发展(Nano Res. 2019; Nanoscale 2019)。
四、主要研究论文(第一作者或通讯作者)
1. Taishan Wang, and Chunru Wang*. Endohedral Metallofullerenes Based on Spherical Ih-C80 Cage: Molecular Structures and Paramagnetic Properties. Acc. Chem. Res., 2014, 47, 450-458.
2. Tai-Shan Wang, Lai Feng, Jing-Yi Wu, Wei Xu, Jun-Feng Xiang, Kai Tan, Yi-Han Ma, Jun-Peng Zheng, Li Jiang, Xin Lu*, Chun-Ying Shu*, and Chun-Ru Wang*. Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C80-Ih. J. Am. Chem. Soc.,2010, 132, 16362-16364.
3. Taishan Wang, Jingyi Wu, Wei Xu, Junfeng Xiang, Xin Lu, Bao Li, Li Jiang, Chunying Shu* and Chunru Wang*. Spin Divergence Induced by Exohedral Modification: ESR Study of Sc3C2@C80Fulleropyrrolidine. Angew. Chem.-Int. Ed., 2010, 49, 1786-1789.
4. Tai-Shan Wang, Ning Chen, Jun-Feng Xiang, Bao Li, Jing-Yi Wu, Wei Xu, Li Jiang, Kai Tan, Chun-Ying Shu*, Xin Lu* and Chun-Ru Wang*. Russian-Doll-Type Metal Carbide Endofullerene: Synthesis, Isolation, and Characterization of Sc4C2@C80. J. Am. Chem. Soc., 2009, 131, 16646-16647.
5. Taishan Wang*, Jingyi Wu, Yongqiang Feng, Yihan Ma, Li Jiang, Chunying Shu and Chunru Wang*. Preparation and ESR study of Sc3C2@C80 bis-addition fulleropyrrolidines. Dalton Trans.,2012, 41, 2567-2570.
6. Taishan Wang*, Jingyi Wu* and Yongqiang Feng. Scandium carbide/cyanide alloyed cluster inside fullerene cage: synthesis and structural studies of Sc3(μ3-C2)(μ3-CN)@Ih-C80. Dalton Trans., 2014,43, 16270-16274.
7. Taishan Wang, Xiaxia Liao, Jizheng Wang, Chunru Wang, Mei-Yee Chan and Vivian Wing-Wah Yam*. Indan-C60: from a crystalline molecule to photovoltaic application. Chem. Commun., 2013, 49, 9923-9925.
8. Bo Wu, Taishan Wang*, Yongqiang Feng, Zhuxia Zhang, Li Jiang and Chunru Wang*. Molecular magnetic switch for a metallofullerene. Nat. Commun., 2015, 6:6468.
9. Yongqiang Feng, Taishan Wang*, Yongjian Li, Jie Li, Jingyi Wu, Bo Wu, Li Jiang, Chunru Wang*, Steering Metallofullerene Electron Spin in Porous Metal-Organic Framework, J. Am. Chem. Soc., 2015, 137, 15055-15060.
10. Yihan Ma, Taishan Wang*, Jingyi Wu, Yongqiang Feng, Li Jiang, Chunying Shu and Chunru Wang*. Susceptible electron spin adhering to an yttrium cluster inside an azafullerene C79N, Chem. Commun., 2012, 48, 11570-11572.
11. Yongqiang Feng, Taishan Wang*, Jingyi Wu, Yihan Ma, Zhuxia Zhang, Li Jiang, Chunhua Ge*, Chunying Shu and Chunru Wang*. Spin-active metallofullerene stabilized by the core of an NC moiety, Chem. Commun., 2013, 49, 2148-2150.
12. Yongqiang Feng, Taishan Wang*, Jingyi Wu, Zhuxia Zhang, Li Jiang, Hongbin Han* and Chunru Wang*. Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@Ih-C80. Chem. Commun., 2014, 50, 12166-12168.
13. Yihan Ma, Taishan Wang*, Jingyi Wu, Yongqiang Feng, Hui Li, Li Jiang, Chunying Shu, and Chunru Wang*. Electron Spin Manipulation via Encaged Cluster: Differing Anion Radicals of Y2@C82-Cs, Y2C2@C82-Cs, and Sc2C2@C82-Cs. J. Phys. Chem. Lett., 2013, 4, 464-467.
14. Yihan Ma, Taishan Wang*, Jingyi Wu a, Yongqiang Feng, Wei Xu, Li Jiang, Junpeng Zheng, Chunying Shu and Chunru Wang*. Size effect of endohedral cluster on fullerene cage: Preparation and structural studies of Y3N@C78-C2, Nanoscale, 2011, 3, 4955-4957.
15. Yongqiang Feng, Taishan Wang*, Jingyi Wu, Lai Feng,* Junfeng Xiang, Yihan Ma, Zhuxia Zhang, Li Jiang, Chunying Shu and Chunru Wang*. Structural and electronic studies of metal carbide clusterfullerene Sc2C2@Cs-C72, Nanoscale, 2013, 5, 6704-6707.
16. Jingyi Wu, Taishan Wang*, Yihan Ma, Li Jiang, Chunying Shu, and Chunru Wang*. Synthesis, Isolation, Characterization, and Theoretical Studies of Sc3NC@C78-C2, J. Phys. Chem. C, 2011, 115, 23755-23759.
17. Yongqiang Feng, Taishan Wang*, Junfeng Xiang, Lihua Gan, Bo Wu, Li Jiang and Chunru Wang*. Tuneable dynamics of a scandium nitride cluster inside an Ih-C80 cage. Dalton Trans., 2015, 44, 2057-2061.
18. Xia-Xia Liao, Taishan Wang*, Jizheng Wang, Jin-Cheng Zheng*, Chunru Wang, and Vivian Wing-Wah Yam*. Optoelectronic properties of a fullerene derivative containing adamantane group. ACS Appl. Mater. Interfaces, 2013, 5, 9579-9584.
19. Zhuxia Zhang*, Taishan Wang*, Bingshe Xu and Chunru Wang*. Paramagnetic and theoretical study of Y2@C81N: an endohedral azafullerene radical. Dalton Trans., 2014, 43, 12871-12875.
20. Zhuxia Zhang*, Yang Liu, Peide Han, Shengyi Zhuang, Taishan Wang*, Shuchang Luo and Bingshe Xu. Metallofullerenes Encaging Mixed-Metal Clusters: Synthesis and Structural Studies of GdxHo3-xN@C80 and GdxLu3-xN@C80. ChemPhysChem, 2015, 16, 295-298.
21. Yongqiang Feng, Jie Li, Zhuxia Zhang, Bo Wu, Yongjian Li, Li Jiang, Chunru Wang and Taishan Wang*. A highly soluble gadofullerene salt and its magnetic properties. Dalton Trans., 2015, 44, 7781-7784.
22. Bo Wu, Yongjian Li, Li Jiang, Chunru Wang, and Taishan Wang*, Spin-Paramagnet Communication between Nitroxide Radical and Metallofullerene, J. Phys. Chem. C, 2016, 120 , 6252–6255.
23. Jie Li, Taishan Wang,* Yongqiang Feng, Ying Zhang, Mingming Zhen, Chunying Shu, Li Jiang, Yuqing Wang and Chunru Wang*, A water-soluble gadolinium metallofullerenol: facile preparation, magnetic properties and magnetic resonance imaging application, Dalton Trans., 2016, 45, 8696-8699.
24.Yongjian Li, Taishan Wang,* Haibing Meng, Chong Zhao, Mingzhe Nie, Li Jiang, Chunru Wang*, Controlling the magnetic properties of dysprosium metallofullerene within metal-organic framework, Dalton Trans., 2016, 45, 19226-19229.
25. Yongjian Li, Taishan Wang*, Chong Zhao, Yu Qin, Haibing Meng, Mingzhe Nie, Li Jiang, Chunru Wang*, A magnetoreception system constructed by a dysprosium metallofullerene and nitroxide radical, Dalton Trans., 2017, 46, 8938-8941.
26. Chong Zhao, Taishan Wang,* Yongjian Li, Haibing Meng, Mingzhe Nie, Jianlei Tian, Chunru Wang*, Awaking N-hyperfine Couplings in Charged Yttrium Nitride Endohedral Fullerenes, Phys. Chem. Chem. Phys., 2017, 19, 26846-26850.
27.Haibing Meng, Chong Zhao, Yongjian Li, Mingzhe Nie, Chunru Wang* and Taishan Wang*, An implanted paramagnetic metallofullerene probe within a metal–organic framework, Nanoscale, 2018, 10, 3291-3298.
28. Chong Zhao, Haibing Meng, Mingzhe Nie, Li Jiang, Chunru Wang*, and Taishan Wang*, Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal–Organic Framework, J. Phys. Chem. C, 2018, 122, 4635-4640.
29. Haibing Meng, Chong Zhao, Mingzhe Nie, Chunru Wang* and Taishan Wang*, Triptycene Molecular Rotor Mounted on Metallofullerene Sc3C2@C80 and Their Spin-Rotation Couplings, Nanoscale, 2018, 10, 18119-18123.
30. Haibing Meng, Chong Zhao, Mingzhe Nie, Chunru Wang,* and Taishan Wang*, Optically Controlled Molecular Metallofullerene Magnetism via an Azobenzene-Functionalized Metal?Organic Framework, ACS Appl. Mater. Interfaces, 2018, 10, 32607–32612.
31.Haibing Meng, Chong Zhao, Mingzhe Nie, Chunru Wang,* and Taishan Wang,* Changing the Hydrophobic MOF Pores through Encapsulating Fullerene C60 and Metallofullerene Sc3C2@C80, J. Phys. Chem. C, 2019, 123, 6265-6269.
32. Along Liu, Mingzhe Nie, Yajuan Hao, Ying Yang, Taishan Wang*, Zdenek Slanina,* Hailin Cong,* Lai Feng,* Chunru Wang, and Filip Uhlik, Ho2O@C74: Ho2O Cluster Expands within a Small Non-IPR Fullerene Cage of C2(13333)-C74, Inorg. Chem., 2019, 58, 4774-4781.
33. Chong Zhao, Haibing Meng, Mingzhe Nie, Xiang Wang, Zhen-Feng Cai, Ting Chen, Dong Wang, Chunru Wang,* and Taishan Wang*, Supramolecular Complexes of C80-Based Metallofullerenes with [12]Cycloparaphenylene Nanoring and Altered Property in a Confined Space, J. Phys. Chem. C, 2019, 123, 12514-12520.
34. Mingzhe Nie, Jin Xiong, Chong Zhao, Haibing Meng, Kun Zhang, Yibo Han, Jie Li, Bingwu Wang*, Lai Feng* , Chunru Wang*, Taishan Wang*. Luminescent Single-Molecule Magnet of Metallofullerene DyErScN@Ih-C80, Nano Res., 2019, 12, 1727-1731.
35. Taishan Wang, Chunru Wang*, Functional Metallofullerene Materials and Their Applications in Nanomedicine, Magnetics and Electronics, Small, 2019,15, 1901522
36. Chong Zhao, Mingzhe Nie, Haibing Meng, Chunru Wang,* Taishan Wang*, Synthesis and Structural Studies of Two Paramagnetic Metallofullerenes with Isomeric C72 Cage, Inorg. Chem., 2019, 58, 8162-8168.
37. Chong Zhao, Haibing Meng, Mingzhe Nie, Qiang Huang, Pingwu Du,* Chunru Wang* and Taishan Wang*, Construction of a short metallofullerene-peapod with a spin probe, Chem. Commun. 2019, 55, 11511-11514.
38. Mingzhe Nie, Le Yang, Chong Zhao, Haibing Meng, Lai Feng,* Peng Jin,* Chunru Wang,* Taishan Wang*, A Luminescent Single-Molecule Magnet of Dimetallofullerene with Cage-Dependent Property, Nanoscale, 2019, 11, 18612-18618.
39. Jie Zhang, Chong Zhao, Haibing Meng, Mingzhe Nie, Qian Li, Junfeng Xiang, Zhuxia Zhang*, Chunru Wang, Taishan Wang*, Size-selective encapsulation of metallofullerenes by [12]Cycloparaphenylene and dissociation using metal-organic framework, Carbon, 2020, 161, 694-701.
40. Chong Zhao, Kai Tan, Mingzhe Nie, Yuxi Lu, Jie Zhang, Chunru Wang, Xin Lu*, and Taishan Wang*. Scandium Tetrahedron Supported by H Anion and CN Pentaanion inside Fullerene C80. Inorg. Chem. 2020, 59, 8284–8290.
41. Mingzhe Nie, Haibing Meng, Chong Zhao, Yuxi Lu, Jie Zhang, Lai Feng,* Chunru Wang, Taishan Wang*, Crystallographic Evidence and Spin Activation for the Russian-Doll-Type Metallofullerene Sc4C2@C80. Chem. Commun., 2020, 56, 10879-10882.
42. Yuxi Lu, Jie Zhang, Chong Zhao, Mingzhe Nie, Chunru Wang*, Taishan Wang*, Zirconium Nitride as a Highly Efficient Nitrogen Source to Synthesize the Metal Nitride Clusterfullerenes. Sci. CHINA Chem., 2021, 64, 29-33.
43. Chong Zhao, Fupin Liu, Lai Feng, Mingzhe Nie, Yuxi Lu, Jie Zhang, Chunru Wang, and Taishan Wang*, Construction of A Double-Walled Carbon Nanoring, Nanoscale, 2021, 13, 4880-4886.
五、主要论著:
1. 王春儒,王太山,甄明明。金属富勒烯—从基础到应用[M]。北京:化学工业出版社,2018。
2. Taishan Wang and Chunru Wang*; Metal Carbide Clusterfullerenes in Endohedral Fullerenes: From Fundamentals to Applications, Yang, S. F. and Wang, C. R. Eds.; World Scientific Publishing: Singapore, 2014; pp 137-152.
3. Taishan Wang and Chunru Wang*; Electron Spin Resonance Studies of Metallofullerenes in Endohedral Fullerenes: Electron Transfer and Spin, Alexey A. Popov Ed.; Springer International Publishing: Switzerland, 2017; pp 159-167
六、授权专利:
1. 一种金属有机骨架化合物-金属富勒烯复合物及其制备方法,发明(设计)人: 王春儒 王太山 冯永强 蒋礼,申请号:201410652890.4 ,申请日:2014-11-17,专利号:ZL 2014 1 0652890.4,授权公告日:2018-03-23。
2. 一种由纳米材料和外加辐射源组成的实现肿瘤血管阻断的肿瘤治疗药物,发明(设计)人: 王春儒 甄明明 王太山 舒春英 张国强 邹头君,申请号:201410366213.6, 申请日:2014-07-29,专利号:ZL 2014 1 0366213.6,授权公告日:2015-05-18。
3. 金属富勒烯单晶纳米颗粒在制备特异性肿瘤血管阻断剂中的应用,发明(设计)人: 王春儒 甄明明 舒春英 王太山 李杰 张国强,申请号:201410365005.4, 申请日:2014-07-29,专利号:ZL 2014 1 0365005.4,授权公告日:2016-05-25。
4. 一种利用磁性微纳材料在交变磁场或射频驱动下破坏肿瘤血管的靶向抗癌药物,发明(设计)人: 王春儒 甄明明 邹头君 舒春英 王太山 ,申请号:201410643728.6, 申请日:2014-11-11,专利号:ZL 2014 1 0643728.6,授权公告日:2019-02-12。
5. 一种高效提取单金属内嵌富勒烯M@C82的方法,发明(设计)人: 王春儒 蒋礼 王太山 李杰 冯永强 朱常锋,申请号:201310747790.5。申请日:2013-12-31。授权公告日:2016-05-18。
6. 一种提高电弧放电法制备C60/C70富勒烯的产率的方法,发明(设计)人: 王春儒 蒋礼 吴波 舒春英 王太山,申请号:201110131949.1。申请日:2011-05-20,授权公告日:2019-02-12。
7. 一种大富勒烯的制备方法及其专用阳极,发明(设计)人: 王春儒 蒋礼 吴波 舒春英 王太山,申请号:201110138848.7。申请日:2011-05-26,授权公告日:2019-02-12。
8.一种富勒烯复合物及其在清除烟气中自由基的应用,发明(设计)人: 王春儒;王太山;蒙海兵。申请号:201710154105.6。申请日:2017-03-15。授权公告日:2019-09-13。
9. 一种内嵌金属富勒烯与环苯撑的稳定复合物及其制备方法,发明(设计)人: 王春儒;王太山;赵冲。申请号:201710728768.4。申请日:2017-08-23。授权公告日:2019-10-25。
10. 金属富勒烯-光活性MOF复合物、其制备方法与应用以及调控金属富勒烯分子磁性的方法,发明专利 201810456709.0,授权日:2020-10-9,发明(设计)人:王春儒;王太山;蒙海兵。
11. 一种金属富勒烯的光磁功能材料及其制备和应用,发明专利 201811333094.9,授权日:2020-12-31,发明(设计)人:王春儒;王太山;聂明哲。
七、科研基金:
1、第四十八批中国博士后科学基金面上一等资助(新结构金属富勒烯的制备及其性质研究,5万,2010年),主持
2、第四批中国博士后科学基金特别资助(基于金属富勒烯的分子顺磁性质研究,10万,2011年),主持
3、国家自然科学基金青年科学基金项目(21203205,26万,新型金属富勒烯的结构与性质研究,2013-01-01至2015-12-31),主持
4、2015年度化学所“一三五”规划培育项目(10万),主持
5、2016年度化学所青年人才培育项目一项(20万),主持
6、北京市自然科学基金面上项目(磁性内嵌稀土富勒烯的分子设计与性质研究,2162050,18万,2016.1-2018.12),主持
7、硅酸盐建筑材料国家重点实验室(武汉理工大学)2016年度开放基金(SYSJJ2016-02,10万,2016.6-2017.6),主持
8、中科院分子科学卓越中心青年创新小组项目(薄膜太阳能电池材料与器件,50万,2017/09-2019/08),课题负责人
9、国家重点研发计划(高能量密度纳米固态金属锂电池研究,子课题:三维网络结构纳米复合正极,2016YFA0202503 ,110万,2016/07-2021/06),课题骨干
10、国家重大科研仪器设备研制专项 (基于原子自旋效应的超高灵敏磁场与惯性测量实验研究装置-化学所子课题,61227902,600万,2013/01-2018/12),主要研究人员
11、中国科学院科研装备研制项目(X波段连续波电子顺磁共振谱仪,278万,2015/01-2016/12),主要研究人员
12、国家自然科学基金面上项目(内嵌金属富勒烯Y2@C79N分子的顺磁性质研究,51672281,62万,2017.01-2020.12),主持
13、国家自然科学基金面上项目(金属富勒烯与碳纳米环主客体系的构筑与转动相关性质,51972309,60万,2020.01-2023.12),主持
14、国家自然科学基金优秀青年科学基金项目(内嵌富勒烯,52022098,120万,2021.01-2023.12)主持
八、荣誉获奖:
1、2010年度中国科学院院长优秀奖
2、2011年度香江学者奖
3、2019年度中国科学院青年创新促进会优秀会员
4、2009年度中国科学院化学研究所青年科学奖特别优秀奖
5、2010年度中国科学院化学研究所青年科学奖特别优秀奖
6、2010年度中国科学院研究生院三好学生标兵
7、2011年度中国科学院王宽诚博士后工作奖
8、2011年度中国科学院化学研究所青年科学奖优秀奖
9、2012年中国分析测试协会科学技术奖(CAIA奖)三等奖(4/6)
10、2014年度中国科学院化学研究所青年科学奖特别优秀奖
11、2015年度中国科学院化学研究所青年科学奖特别优秀奖
12、2015年度中国科学院北京分院科技成果转化奖二等奖
13、2015年度中国科学院青年创新促进会会员
14、2018年度中国科学院化学研究所青年科学奖特别优秀奖